Spectral Analysis of Chemical Time Series from Long-Term Catchment Monitoring Studies: Hydrochemical Insights and Data Requirements

Hydrological and hydrochemical data from long-term monitoring stations are vital for inferring travel times and flowpaths of water, and transport of contaminants through catchments. Spectral analysis is particularly powerful for studying the hydrological and chemical dynamics of catchments across a wide range of time scales. Here, recent work is reviewed that illustrates how spectral analyses of long-term monitoring data can be used to infer the travel-time distribution of water through catchments, and to measure the chemical retardation of reactive solutes at the catchment scale. For spectral analysis, it is desirable to have data sets with high sampling frequency and long periods of coverage. Using two data sets, a 3-yr daily data series and a 17-yr weekly data series from the Hafren catchment at Plynlimon, Wales, we demonstrate that high-frequency sampling (e.g., daily or more frequent) is particularly useful for revealing the short-term chemical dynamics that most clearly reflect the interplay of subsurface chemical and hydrological processes. However, data sets that combine high-frequency sampling during storm events with low-frequency sampling between storms can cause spectral artifacts and must be treated with special care.     

PREDICTING INFLUENCES OF URBAN DEVELOPMENT ON THERMAL HABITAT IN A WARM WATER STREAM1

ABSTRACT: Watershed and aquatic ecosystem management requires methods to predict and understand thermal impacts on stream habitat from urbanization. This study evaluates thermal effects of projected urbanization using a modeling framework and considers the biological implications to the fish community. The Stream Network Temperature Model (SNTEMP) was used in combination with the Hydrologic Simulation Program Fortran (HSPF) to assess changes in stream thermal habitat under altered stream‐ flow, shade, and channel width associated with low, medium, and high density urban developments in the Back Creek watershed (Roanoke County, Virginia). Flow alteration by the high density development scenario alone caused minimal heating of mean daily summer base flow (mean +0.1°C). However, when flow changes were modeled concurrently with reduced shade and increased channel width, mean daily temperature increased 1°C. Maximum daily temperatures exceeding the state standard (31°C) increased from 1.1 to 7.6 percent of the time using summer 2000 climatic conditions. Model results suggest that additional urban development will alter stream temperature, potentially limiting thermal habitat and shifting the fish community structure from intolerant to tolerant fish species in Back Creek. More research is needed on the sub‐lethal or chronic effects of increased stream temperature regimes on fish, particularly for those species already living in habitats near their upper limits.     

Measuring road traffic safety performance: monitoring trends in nonfatal injury

Traditional indicators used to monitor trends in nonfatal injury are influenced by a range of factors other than the incidence of injury. Indicators based on threat-to-life scales offer a means of addressing this problem. The aim of the research described in this article was to compare trends in the official indicators with trends in selected threat-to-life indicators. We compared indicators based on the New Injury Severity Score and the International Classification of Diseases-based Injury Severity Score with the official New Zealand indicators; namely, (1) reported injuries, (2) reported injuries per 10,000 vehicles, (3) reported injuries per 100,000 people, and (4) number hospitalized (discharges). All the official indicators suggest that there has been a substantive decline in nonfatal Motor Vehicle Traffic Crashes (MVTCs) for the period 1988-2000, but a notable increase in 2001. The latter appear to be artifactual increases due to changes in patterns of data collection and do not reflect any real changes in incidence. Further support for this is provided by the results for the two threat-to-life indicators, which suggest that the decline observed for 1988-98 may have been attributable to a decline in the ascertainment or occurrence of minor injuries since those injuries, which represent a significant threat to life, have not declined to the same degree. Given the prominence of motor vehicle crashes as a cause of unnecessary morbidity, more thought needs to be given to deriving valid indicators for measuring trends in serious nonfatal injury.     

Levels and trends of polybrominated diphenylethers and other brominated flame retardants in wildlife

In this paper, we review the available data for polybrominated diphenylethers (PBDEs) and other flame retardants in wildlife, with the exception of fishes from Europe and North America which are covered in more detail elsewhere. More data are available for PBDEs than for other compounds, and these show that some of these compounds have become widely distributed in the environment, being found in samples from Europe, Australia, Azerbaijan, North America and the Arctic. Most available data relate to birds and their eggs and marine mammals, but the results of two food web studies are also included. The detection of PBDEs in pelagic marine mammals which feed in deep offshore waters, including baleen whales, indicate that these compounds have found their way into deep-water, oceanic food webs as well as the coastal/shallow sea examples described in detail. In the North Sea study, the most marked increase in lipid-normalised concentrations of six BDE congeners occurred during transfer from predatory fish to marine mammals. In the St. Lawrence Estuary study, marked differences in the ratios observed between species suggested that some fish species may be able to metabolise BDE99.A number of time trend studies have also been conducted, notably in guillemot eggs from Sweden (1969-2000), beluga whales from the Canadian Arctic (1982-1997 and 1989-2001) and from the St. Lawrence Estuary (1988-1999), and ringed seals from the Canadian Arctic (1981-2000). In the temperate latitudes, from these and other studies (e.g. in dated sediment cores), PBDE concentrations began to rise earlier than in those from high latitudes, in line with data for production and use. These trends have now slowed in many cases. Declines could be expected in Europe for many congeners following the cessation of manufacture and use of the penta-mix formulation in the EU, though these are not yet apparent in environmental samples. In Arctic biota, however, the rapidly rising concentrations seen currently in Canada could be expected to continue for some time, reflecting continued production and use of the penta-mix formulation in North America (>95% of the world total) and the impact of long-range atmospheric transport.     

Changing places, changing emissions: The cross-scale reliability of greenhouse gas emission inventories in the US

Greenhouse gas (GHG) emission inventories, which currently inform abatement policy discussions, are developed mostly from national scale data. Nevertheless, although the policy debate tends to take place in global and national arenas, action to abate GHG emissions is inherently within the provenance of local institutions and communities. The purpose of this paper is to examine how much information is lost by not estimating GHG emissions data at scales finer than the whole US. Such information may be critical in bridging global and local policy. Differences in the composition of GHG emission sources based on GHG emission inventories at three nested spatial scales (national, state, local) for four study sites (in Kansas, North Carolina, Ohio and Pennsylvania) are analysed, drawing upon initial results of a large collaborative study known as the 'Association of American Geographers-Global Change in Local Places (GCLP)' project. The concept of spatial sovereignty of emissions is developed to test the cross-scale reliability of emission inventories. For the test year 1990, close agreement is found in the by-gas composition of GHG emissions among national, state and local inventories. Spatial sovereignty in this case is maintained. However close agreement is not found in the by-source composition of GHG emissions among national, state and local inventories. Spatial sovereignty in this case is not maintained. Regular compilation of state and local emissions source inventories may be necessary to track important spatial and temporal deviations from national trends.     

Linking National Sustainable Development Strategy and Local Implementation: a case study in Sweden

Sweden has led the way in Europe in environmental protection, ecologically based technological innovation and social democracy. As new economic and ethnographic realities impact upon it, it faces challenges to its policies and practices long familiar elsewhere in Europe. We report on a study for the Swedish Research Councils in which we examined the national framework and political strategy for sustainable development, and how the strategy is being implemented in Sweden's three major cities and two case-study municipalities. History and tradition, cultural homogeneity and a strong and shared sense between sectors of 'the public good', emerged as very important. Until recently, these have obviated the need for formal links between the environmental, social and economic agendas. They now appear inadequately developed at all levels of governance. Tensions in policy are being played out at the level of the municipality, to which power is highly devolved, and Local Agenda 21, interpreted as project rather than process, seems unequal to the task of integration. We suggest what lessons may be drawn from the Swedish experience if issues of power and trust, leadership and participatory vs representative democracy are to be resolved.     

What Price Cheap Food?

This paper is the report of a meetingthat gathered many of the UK's most senioranimal scientists with representatives of thefarming industry, consumer groups, animalwelfare groups, and environmentalists. Therewas strong consensus that the current economicstructure of agriculture cannot adequatelyaddress major issues of concern to society:farm incomes, food security and safety, theneeds of developing countries, animal welfare,and the environment. This economic structure isbased primarily on competition betweenproducers and between retailers, driving foodprices down, combined with externalization ofmany costs. These issues must be addressed by acombination of legislation, restructuring ofthe market, and use of public funds. Themeeting included workshops that made otherrecommendations for research and education. Themost urgent requirement is recognition thatchange is needed and development of a visionfor what that change must achieve.     

Distribution and ecotoxicity of chlorotriazines in the Scheldt Estuary (B-Nl)

As part of the Endis-Risks project, the current study describes the occurrence of the chlorotriazine pesticides atrazine, simazine and terbutylazine in water, sediment and suspended matter in the Scheldt estuary (B-Nl) from 2002 to 2005 (3 samplings a year, 8 sampling points). Atrazine was found at the highest concentrations, varying from 10 to 736 ng/l in water and from 5 up to 10 ng/g in suspended matter. Simazine and terbutylazine were detected at lower concentrations. Traces of the targeted pesticides were also detected in sediments, but these were below the limit of quantification. As part of an ecotoxicological assessment, we studied the potential effect of atrazine on molting of Neomysis integer (Crustacea:Mysidacea), a resident invertebrate of the Scheldt Estuary and a proposed test organism for the evaluation of endocrine disruption. Following chronic exposure ( approximately 3 weeks), atrazine did not significantly affect mysid molting at environmentally relevant concentrations (up to 1 microg/l).